Get A Guide to Monte Carlo Simulations in Statistical Physics, PDF

January 30, 2018 | Thermodynamics And Statistical Mechanics | By admin | 0 Comments

By David P. Landau, Kurt Binder

ISBN-10: 0521842387

ISBN-13: 9780521842389

I agree that it covers loads of themes, a lot of them are very important. they really comprise even more issues within the moment variation than the 1st one. even though, the authors seldomly speak about one subject greater than a web page. it is like interpreting abstracts of papers. So in case you already recognize the stuff, you don't want this e-book. simply opt for a few papers (papers are not less than as much as date). for those who do not know something approximately Monte Carlo sampling, this e-book will not assist you an excessive amount of. So do not waste your cash in this ebook. Newman's publication or Frenkel's ebook is far better.

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Extra resources for A Guide to Monte Carlo Simulations in Statistical Physics, Second Edition

Sample text

At the capacitance minimum) is given by the diffuse layer, C ∼ = CGC (0, c). Therefore the ratio of capacitances in these conditions should be close to the RF for the surface of the solid metal M: R≡ Capp M C Hg (31) It became clear later that this treatment had certain defects. The data for most dilute solutions (typically, within mM range) are especially sensitive to various experimental errors, while the capacitance values to be measured are very low. Another weak point of the reasoning is the assumption that the solid surface is uniform, which is hardly justified, as we see in the following text.

The diffuse-layer capacitance, Eqs. (21a) and (21b), is growing with the increase of the absolute value of the charge and with the concentration. c. 001 M aqueous solution of a 1,−1 electrolyte. c. As a result, for sufficiently concentrated solutions, about 1 M or higher, the diffuselayer contribution in Eq. (20) represents in most cases only a minor correction to the compact-layer term. Then, one can even use the simple Helmholtz model for qualitative interpretation of the data. , this approximation is acceptable for all concentrations.

For example, electrophoresis, the movement of colloidal particles with respect to the solution under the influence of an external electric field, originates from the displacement of the particle and the mobile part of its EDL in the opposite directions under the action of this field, since these components of the system possess charges of opposite signs. A related phenomenon occurs if the solid particles move with respect to the solution, for example, under the influence of the gravity force (sedimentation).

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A Guide to Monte Carlo Simulations in Statistical Physics, Second Edition by David P. Landau, Kurt Binder


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